Detonation performance of urea-hydrogen peroxide (UHP)**

Francis Halleux, Jean François Pons, Ian Wilson, Bart Simoens, Romuald Van Riet, Michel Lefebvre

Onderzoeksoutput: Bijdrage aan een tijdschriftArtikelpeer review

Samenvatting

Carbamide Peroxide, an adduct of Urea and Hydrogen Peroxide, is commonly used in the cosmetic and pharmaceutical industries as a solid source of hydrogen peroxide. However, it exhibits explosive properties and can be easily manufactured from readily available household chemicals, making it a potential emerging threat. We carried out a detailed performance assessment, combining experiments, thermochemical calculations and numerical simulations and highlighted a good level of agreement between experimental data from lab, field and underwater firings. A maximum detonation velocity of 3.65 km/s was recorded for unconfined 25 kg UHP charges at 0.85 g/cm3 (200 mm charge diameter). We determined in these conditions an infinite diameter detonation velocity of 3.94 km/s. These results are also consistent with previous results obtained at small scale under heavy confinement. Airblast measurements highlighted an average 40 % TNT equivalence for impulse and 55 % for peak overpressure at short distance, which are in good agreement with the 57 % (Power Index) calculated from Explo5, while 50 % for bubble energy (explosive power) and 20 % for shock pressure (brisance) were obtained from underwater experiments. The use of different experimental approaches has proven useful to characterise the performances parameters of a non-ideal explosive for risk assessment purposes.

Originele taal-2Engels
Artikelnummere202300011
TijdschriftPropellants, Explosives, Pyrotechnics
Volume48
Nummer van het tijdschrift6
DOI's
StatusGepubliceerd - mei 2023

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